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PDF | The majority of oral diseases present as growths and masses of varied cellular origin. Such masses may include simple hyperplasia. The presence of a neurovascular hamartoma within the oral cavity is truly a rare entity. Scarcely reported in the literature, these hamartomas. Cowden’s Syndrome, Bannayan-Riley-Ruvalcaba Syndrome, PTEN Hamartoma Tumour Syndrome.

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Sign up with Facebook Sign up with Twitter. I don’t have a Facebook or a Twitter account. The prevalence has been estimated at one in[Nelen et al ], likely an underestimate.

Individuals with CS are at high risk for breast, thyroid, and endometrial cancers. As with other hereditary cancer syndromes, the risk of multifocal and bilateral in paired organs such as the breasts cancer is increased:. Median age of onset was 37 years; seven years was the youngest age at diagnosis [Ngeow et al ]. Histologic findings varied, ranging from ganglioneuromatous polyps, hamartomatous polyps, and juvenile polyps to adenomatous polyps. Brain tumors as well as vascular malformations affecting any organ are occasionally seen in individuals with CS.

Hamartomas of the oral cavity.

Because meningioma is so common in the general population, it is not yet clear if meningioma is a true manifestation of CS. A rare central nervous system tumor, cerebellar dysplastic gangliocytoma Lhermitte-Duclos disease is also found in CS and may be pathognomonic.

Simvastatin has been cagity to exhibit antitumor effects, and so the aim of the present study was to assess the effects of simvastatin on the growth of human PTEN haploinsufficient lipoma cells.

The results of the present study suggest that simvastatin may be beneficial for patients with inoperable PTEN haploinsufficient lipomas. Phosphatase and tensin homolog PTEN is one of the most frequently inactivated tumor suppressors in breast cancer.

Mosaicism is the presence of two or more genetically distinct cell lineages originating from a single zygote. The skin frequently marks hamqrtomas conditions through migration patterns of a population of mutant cells during embryogenesis. In addition to revealing spatially distinct roles of PI3K isoforms in the skin, these findings provide a rationale for use of PI3K inhibitors to prevent and treat hamartomas in patients with PHTS. This review highlights these rare syndromes and their tumour pathology, including Peutz-Jeghers syndrome gastric type mucinous carcinoma of the cervix; ovarian sex cord tumour with annular tubules ; hereditary leiomyoma renal cell carcinoma syndrome uterine leiomyoma ; tuberous sclerosis complex uterine PEComa; uterine lymphangioleiomyomatosis ; DICER1 syndrome ovarian Bamartomas cell tumour; cervical embryonal rhabdomyosarcoma ; rhabdoid tumour predisposition syndrome 2 small cell carcinoma of the ovary, hypercalcaemic type ; Cowden syndrome endometrial endometrioid adenocarcinoma ; naevoid basal cell carcinoma syndrome ovarian fibroma ; and Von Hippel-Lindau syndrome clear cell papillary cystadenoma of the broad ligament.

In this study, we report that specific gene targeting of phosphatase and tensin homolog PTEN in smooth muscle cells caused age-related colonic lymphoid hyperplasia followed by global immune activation in mice. Research and publish the best content. Hamartomas of the oral cavity.

Hamartomas of the oral cavity

Sign up to comment. Your new post is loading Scooped by Emmi Dack. Pilot data suggest that individuals with CS and Cowden-like syndrome with a germline KLLN epimutation have a greater prevalence of breast and renal cell carcinomas than do those with a germline PTEN pathogenic variant. As with other hereditary cancer syndromes, the risk of multifocal and bilateral in paired organs such as the breasts cancer is increased: Benign uterine fibroids are common.

The predominant histology is papillary renal cell carcinoma [Mester et al ]. Syndromic autism spectrum disorders: At 9 years of age, his head circumference was 6 SD above the mean.

He inherited the missense mutation from his intellectually and socially normal mother, who was subsequently diagnosed with CS. The Turkish Journal of Pediatrics: Polyposi s deserves a perfect physical examination for final diagnosis: Association of genetic polymorphisms in PTEN and additional interaction with alcohol consumption and smoking on colorectal cancer in Chinese population.

Hamartomas of the oral cavity | Cow

To investigate the association of phosphatase and tensin homologue deleted on chromosome ten PTEN gene rs, and additional interaction with drinking and smoking on colorectal cancer CRCbased on a hospital based Chinese case-control study.

Rare diseases in general practice: These years can be defined by uncertainty, multiple hospital attendances, investigations, misdiagnoses, and inappropriate treatments; with huge emotional cost and wasted time, effort and resources. Even in the absence of a disease-specific therapy, a prompt and accurate diagnosis is of huge value. It can help inform family planning, especially for inherited paediatric diseases where several children in a family may be affected before diagnosis, it informs prognosis and importantly, it assists the patient and family in gaining access to social and educational support.

Radiation induced breast cancer risk in BRCA mutation carriers from low-dose radiological exposures: The lack of paediatric reports of PHTS-associated cancer may be explained by previous diagnostic limitations. We recommend yearly physical examination particularly of skin and thyroid and yearly thyroid ultrasound upon diagnosis.

In view of the high lifetime risk of malignancy it is important to keep patients under close surveillance. Epub Jun Experimental drug suppresses new defective PTEN cancer pathway, study finds. Uncommon hereditary gynaecological tumour syndromes: Several autosomal dominant inherited tumour syndromes demonstrate prominent features in the oral and maxillofacial region. Although multiple organ systems are frequently involved, the target organs more frequently affected are the skin nevoid basal cel.

PTEN in smooth muscle cells is essential for colonic immune homeostasis. Targeting Strategies from Gene to Protein. This observation is consistent with prior experimental studies in cell culture, which have predicted an association between germline PTEN loss-of-function mutations and hypersensitivity of normal tissues to radiotherapy. Caution with radiotherapy is recommended until this observation can be studied further in larger cohorts of Cowden syn- drome patients.

Benign thyroid lesions and single cases o. How do I publish content on my topic? How to grow my audience and develop my traffic?

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Hamartomas of the oral cavity

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Loxoscelismo cutáneo. NO. Alta a domicilio con dapsona, aplicación de hielo local intermitente y vigilancia de evolución clínica. Loxoscelismo cutáneo- visceral. Abstract. ANGULO-CASTANEDA, Nancy Yaneth and CASTANO-ARIAS, Paula Andrea. Cutaneous Loxoscelism: Patient with multiple bites and contraindication . Resumen. MANRIQUEZ M, Juan J y SILVA V, Sergio. Cutaneous and visceral loxoscelism: A systematic review. Rev. chil. infectol. [online]. , vol, n

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In the year has been indexed in the Medlinedatabase, and has become a vehicle for expressing the most current Spanish medicine and modern.

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Anton Szandor LaVey – Biblia Szatana. 9 likes. Book. 2 Called “The Black Pope” by many of his followers, Anton LaVey began the .. Lavey Anton Szandor – Biblia Szatana wyświetleń,67 stron. Anton Szandor LaVey, zalozyciel Kosciola Szatana w San Francisco, znany najbardziej ze swojej kontrowersyjnej ksiazki Biblia Szatana, jednak to Szatanska.

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Published by FOX first published To see what your friends thought of this book, please sign up. To ask other readers questions about Biblia Szatanaplease sign up. I want to know where I can read this for free. Eddy Klein It’s at my local library. It’s probably at yours too. See 2 questions about Biblia Szatana…. Lists with This Book. This book is not yet featured on Listopia. Needlessly blunt, socially irresponsible, poorly written.

The work bibliaa a person who knows nothing about human nature and assumes man’s greatest evil is receiving handjobs from a peepshow tent girl.

Anybody who needs a book to tell them that it is within their power to do a ton of drugs, have sex with whomever they choose and have cake for dinner will not go far in life. View all 15 comments.

Lagey Mountain Toothless Hayseed Bibkia. I read this book in high school. The reason for the one star is that it serves at least some positive use in that it corrects some Christians belief about what “philosophical Satanism” entails.

LaVey doesn’t believe in anything like the biblical concept of Satan. It’s meant to be something like the antithesis of Christian morality. So whereas Jesus says “Turn the other cheek” LaVey says, “If a man smite you on the cheek, smite him twice as hard on the other.

LaVey holds to some kind of ethical egoism. But one wonders why he tries to advocate for that thesis. If one has a good moral theory, it seems that it should lqvey pronounced. But if Ethical Egoism is true, it would seem that its adherents, those who have grasped and understood its truth, shouldn’t teach it to others. It would seem that if most people were taught the ethics of altruism, this would be the best situation for the egoist. Thus it would seem that if Ethical Egoism were true, its adherents should teach that it is false and that Altruistic Ethics is the correct theory.

But this seems to undermine szatanna feature of morality. Moral principles serve as action guides that inform us how to act in situations.

Moral precepts should be lqvey. Publicized so that others are morally informed agents.

But if Ethical Egoism were true, not only would it be unwise for me to teach it, it just might be immoral for me to teach it. Teaching others to be egoists could easily turn out to be not in our best interest. And, principles should be taught since moral principles serve as action-guides to help resolve among other things interpersonal conflict.

Furthermore, since Ethical Egoism isn’t so crass as to say that we should do what benefits us in the here and now, but is a long-term plan, spanning across all of our future selves, it might not be in our best interest, considering all our selves, to promulgate Ethical Egoism to ourselves.

Thus we shouldn’t teach Ethical Egoism to ourselves. And, if we should, what is the morally relevant reason that allows us to discriminate between ourselves and others? This is one reason why ethicist Russ Shafer-Landau has pointed out the Ethical Egoism seems to imply that we should discriminate against people. Treat ourselves as special over against other humans. But this radical prejudice seems unfounded. If a moral principle P cannot be universalized, then I shouldn’t teach it to myself even.

If it can’t be universalized, it doesn’t even seem like a moral principle. But of course LaVey dislikes altruism. But we can quickly see the moral problems that pop up real quick: I did it for myself. After all, my life would suck if you weren’t in it, and there’s that matter of the 1, dollars you owe me.

It wouldn’t be beneficial for me to lose out on that. So, you’re welcome, friend. Not many, I’d wager. But, don’t those adhering to ethical egoism say that they can account for “altruism? That their system doesn’t do away with our moral responsibility to help others, for the sake of helping others? But, isn’t this a trick? Doesn’t this, in fact, fail to distinguish between pseudo and genuine altruism? The latter has, as its goal, purpose, and intrinsic value, the benefit of another irrespective of benefit to one’s self?

And, as an aside, that there may be personal payoffs and side effects does not logically entail that the moral action was done for egoistic reasons as its basis.

Sure it is nice to have your friend around and to collect on the 1, but an altruistic act is done solely for the sake of the other; even though there might very well be side effects and outcomes that are good for bibliq, personally. Of course egoists like LaVey try to make altruistic acts ft within their moral philosophy.

But above I’ve pointed out that the cost is to defend pseudo altruism over against genuine altruism. And, the argument from side effects does not imply ethical egoism. Indeed, most of us, including Smith, might rightly look down on LaVey’s actions. Speaking to intention, altruistic acts, done on and for egoism’s premises, are morally repugnant acts. There’s plenty other dubious ethical statements. And he also seems a bit arbitrary.

For example, he says: Apparently we can kill them, after all, at one place he writes, ” If a guest in your lair annoys you, treat him cruelly and without mercy. For example, he claims: If someone bothers you, ask him to stop.

Biblia Szatana by Anton Szandor LaVey (2 star ratings)

If he does not stop, destroy him. LaVey fails lavsy regard to having a just ethical system. LaVey also makes suspect metaphysical claims, and that’s putting it mildly. We could call it sophomoric, but that would be unfair to sophomores! He advocates practicing saztana and advocating it’s power. Puh-lease I probably would have rated it 5 stars in high school because I was a big tough-guy who had a superority complex, just like LaVey.

Bbilia yeah, I was unregenerate too. Such a time-sensitive rating. Ten years ago I would’ve lavished this book with idealistic praise and five stars. Also, I can’t believe that I actually read this, then again I used to don a pentagram necklace and wear dresses to school, so View all 6 comments. View all 7 comments. I wasn’t able to finish this book because it gave me a massive headache while reading it.

Biblia Szatana

I’m not religious, nor am I a “satan worshipper. A majority of this book’s context went against my own personal outlook on human nature, and my morals as a human being.

Judgmental, frustrated, socially irresponsible, szatnaa, and hostile, LaVey’s writing was unimpressive and simply lacked substance. Poorly written, and not I wasn’t able to finish this book because it gave me a massive headache while reading it. Lavy written, and not a book that should be taken as “serious literature” by its readers.

If they can actually manage to get through the entire book This is supposed to be a system of belief, but LaVey changes his mind halfway through. First he states that one should look only after the self, but then he includes those you love as well. It’s not very consistent, and definitely difficult szztana keep on task reading it.

At the end you’ve got an ethical system that is inconsistent at best, and szaana should have been replaced with ethical egoism. But that wouldn’t be as out there as LaVey seems to be seeking.

Much of the details are seemingly there Viblia is supposed to be a system of belief, but LaVey changes his mind halfway through. Much of the details are seemingly there for shock value, and not so much for actual point. Since LaVey makes it clear that no one really believes in Satan, I don’t know why he didn’t go with ethical egoism, when that means you don’t have to dress up in silly robes every so often and find an excuse to have sex in front of others.

IMM 5551 PDF

Should I use the guidance of IMM E OR THE E? Which one is applicaple to me? 2. Should I pay the fees of $75 or $? 3. Should I. the guide Applying to Change Conditions or Extend Your Stay in Canada as a Visitor (IMM ). The guide may be obtained by visiting our Web site or you can. Instruction Guide (IMM ). This application is for temporary residents who are already in Canada as visitors and wish to: Extend their stay;; Change the.

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This is not a legal document. This guide is designed to help you determine if you are eligible to apply for an extension or change conditions of your stay in Canada as a visitor. It provides all the necessary information, instructions, and application forms for you to complete and submit. The application for an eTA must be made online.

Find out if you need to give biometrics. You only need to give your biometrics 55511 every 10 years. Find out if your biometrics are still valid and when they expire by using the Check Biometric Status Tool. Visitors are a class of temporary resident who are legally authorized to enter Canada temporarily to holiday, visit family, conduct business, etc.

Application to Change Conditions or Extend Your Stay in Canada as a Visitor

They are restricted in length of stay and are subject to various other conditions. If your current temporary resident status is still valid you can apply for an extension of your stay. For any permit, you should always apply at least 30 days before your current status expires. Your original temporary status as a visitor continues under the same conditions until your application is finalized and you have been notified of the decision. The validity of your temporary resident status cannot exceed the validity of your passport.

Therefore, you should ensure that your passport will be valid for at least the same amount of time as your requested extension. Each member of your immediate family spouse or common-law partner, dependent children who wishes to remain longer in Canada must apply for permission to do so.

If you all apply at the same time for an extension, each person has to submit a separate application form. All appropriate documentation and the required fee for each person must also be included. If your status has expired or if you did not respect one of the conditions of your permit or you have worked or studied without a required permit, you have committed an offence under the Immigration and Refugee Protection Act.

You may be subject to an admissibility hearing that could lead to removal from Canada. If your temporary resident status has expired, do not apply for an extension as you are not eligible. Ijm, if you wish 55551 stay in Canada after your status has expired you may apply for restoration of status within 90 days of your offence loss of status or you must leave Canada.

If you wish to apply for restoration, complete the enclosed application providing full details of how you came to jmm the offence. There is no guarantee that your application will kmm accepted. See the section Restoration of Status.

It is illegal to remain in Canada beyond the validity of your status in Canada. After reading this guide, if you believe you are eligible to apply then jmm should proceed as instructed below:.

The Case Processing Centre will review your application to determine if it is complete. If your application is not signed, if all mandatory sections are not completed, or if the required fee is missing, your application will be returned to you and you will have to re-apply. If you reapply after 55551 current status has expired, you will need to apply for restoration of status.

If your application is referred to a local office, they will contact you to obtain additional information or clarification and if required, invite you to an interview. It may take up to three months for them to contact you. Once they receive the additional imn or clarification, the local office will complete the final stages 55551 processing.

The local office will notify you by mail of their decision. The Case Processing Centre receives large volumes of applications in the temporary resident categories each year. However, you may want to apply in advance of this recommended period since processing delays vary. Check our current processing times. Parents and Grandparents already in Canada on a temporary resident status may apply to extend their stay through the Case Processing Centre by using this application package.

All persons authorized to enter Canada who are not Canadian citizens or permanent residents are authorized to enter as temporary residents as a visitor, student or worker. When they enter Canada they are given temporary resident status for a limited period of time. If you find a stamp, it should look like one of these. For example, if the officer specified a date as shown in the above illustration, your temporary resident status would expire on June 30 th If there is no stamp, a handwritten date or document in your passport, your temporary resident status will expire six months from the day you arrived in Canada.

If you were given a visitor record, study or work permit, the expiry date is marked on the document.

When applying to change conditions or extend your stay in Canada, you are required to submit photocopies of passport pages clearly showing the stamp made by Canadian authorities on your most recent entry to Canada. If you did not require a passport to enter Canada, your temporary resident status will expire six months from the day you entered Canada unless you were given a visitor record, study or work permit.

Temporary residents and visitor visa extension | Apply To Canada

If you were given a imk, the expiry date is marked on it. You may apply as many times as you wish, but each time that you apply, you i,m complete a new application and pay the fee. You must also demonstrate that your residence in Canada is still temporary.

However, if you leave temporarily and you do not have a new document to re-enter Canada, you will have to re-apply either at the port of entry, if you have the right to do so, or at a visa office and pay another processing fee to receive a decision.

In order to return to Canada, you must be in possession of a valid passport or travel document. You also need to hold 5551 valid study or work permit if you are returning immm study or work in Canada. If you are a citizen of a country or territory that requires a temporary resident visa TRV or an eTA to travel to Canada, you will also need to be in possession of a valid entry visa or an eTA to return, unless:.

Possession of these documents does not guarantee re-entry. All persons must establish that they im all of the requirements of The Immigration and Refugee Protection Act and Regulations before being authorized to enter or re-enter Canada. It is possible that you will not be able to enter Canada. The final decision is always made by the officer at the port of entry. Citizens of the United States U. Lawful permanent residents of the U.

Application to Change Conditions or Extend Your Stay in Canada as a Visitor –

Pierre and Miquelon by air. You may be able to restore your status as a visitor, student or worker within 90 days of losing it, if you lost it because:. You may still be eligible for restoration if you continue to meet the initial requirements for your stay and have not failed to comply with other conditions imposed. If you wish to obtain a new study or work permit and restore your temporary resident status, you must. Restoration applies to each family member who has lost his or her status.

There is no guarantee that we will accept your application. An officer will evaluate your request for restoration of status and if approved will process your application for a study or work permit. You will then be advised of any further action to be taken. You may not study or work in Canada until your application for restoration has been processed. The documentation you provide will be used to establish that your authorization to remain in Canada would not be contrary to the Act.

You must provide truthful, accurate information. The information provided may be verified. Processing will stop immediately if you give false or misleading information.

It is an offence under section of the Immigration and Refugee Protection Act to knowingly make a false statement on this form. This form must be completed by each person who wants to apply for an extension of their stay, temporary resident permit or change conditions of their stay in Canada, including applying for an initial temporary resident permit. The application must be signed and dated.

Completing the form electronically is easier and reduces the risk of errors that can slow down the application process. From the list, select the language English or French in which you would like to receive your service.

Type your family name surname as it appears on your passport or travel document even if the name is misspelled. Do im, use initials.

If you do not have a family name on your passport or travel document, enter all your given names here and leave the given name field blank. Type all of your given names first, second, or more as they appear on your passport or travel document even if the name is misspelled. If you do not have a given name on your passport or travel document, leave this field blank.

Check the box to indicate if you ever used any other name. This could include your birth name, maiden 551, married name, nick name, etc. Indicate your date of birth. Note, if your city, town, or country of birth is indicated in your passport or your travel document, please record it as it appears in the document. From the list, select your country of citizenship. To be a citizen of a country means that you iimm either born in that country in most cases or have been granted citizenship by that country.

If you have dual citizenship, select the country that issued the passport you will be using for this trip. This section must be completed if you selected “Other” 551 a status. Check the box to indicate whether you have lived in any country other than your country of citizenship or your current country of residence for more than six 6 months in the past five 5 years.

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Make sure there is no space between each number or letter. From the list, select the name of the country or territory that issued your passport or travel document. For this trip — Check Yes or No to tell us if you are using a passport issued by the Ministry of Foreign Affairs in Taiwan that shows your personal identification number.

Check Yes or No to tell us if you have a national identity document.


About Edmond Demolins: French pedagogue and journalist. His most known works are the works on social geography: Anglo-Saxon superiority: to what it is. Anglo-Saxon Superiority to What It Is Due has 2 ratings and 1 review. Pat said: Kind of relevant in this times of A Europe of multiple speeds. The auth. Anglo-Saxon Superiority by Edmond Demolins, , available at Book Depository with free delivery worldwide.

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Edmond Demolins — was a French pedagogue. Edmond Demolins was born in in Marseille. He formed a small group of students including Paul de Rousiers that met in Le Play’s salon every Monday in the s. This small group functioned as a true research team. Edmond Demolins died in in Caen.

Life and work Edmond Demolins was born in in Marseille. Progressive education is a pedagogical movement that began in the late nineteenth century; it has persisted in various forms to the present. The term progressive was engaged to distinguish this education from the traditional Euro-American curricula of the 19th century, which was rooted in classical preparation for the university and strongly edmolins by social class. By contrast, emond education finds its roots in present experience.

A quoi tient la supériorité des Anglo-Saxons

Most progressive education programs have these qualities in common[1]: Emphasis on learning by doing — hands-on projects, expeditionary learning, experiential edmpnd Integrated curriculum focused on thematic units Integration of entrepreneurship into education Strong emphasis on problem solving and critical thinking Group work and development of social skills Understanding and action as the goals of demolin as opposed to rote knowledge Collaborative and cooperative learning projects Education for social responsibility and democracy Highly personalize Ahmad Fathy Zaghlul — was an Egyptian nationalist lawyer and politician.

He had several administrative and government posts, and at one point was Deputy Minister of Justice. In he was amongst the Egyptian judges at the summary trial for the Denshawai Incident, which damaged his popular reputation in Egypt. Although part of the ruling Ottoman dynasty himself, through his mother, Sultanzade Sabahaddin was known as a Young Turk and thus opposed to the absolute rule of the dynasty. Prince Sabahaddin was born in Constantinople in Life Born in Paris on 19 Marchhe was trained in the catholic seminary of Issy-les-Moulineaux and in the law school of the Sorbonne university in Paris.

He always had a poor health and dedicated most of his life to writing from his family estate of Tourville, where he had to retire after only a few years of work as a priest in Paris.

There he would edmonv receive and counsel his many disciples and friends. He wrote only one book but developed his thinking through an extremely abundant correspondence. He died in Tourville castle on 5 March Thought Social science Herri de Tour Social geography is the branch of human geography that is most closely related to social theory in general and sociology in particular, dealing with the relation of social phenomena and its spatial components.

Though the term itself has a tradition of more than years,[1] there is no consensus on its explicit content. Bedales School is a co-educational, boarding and day independent school in the village of Steep, near the market town of Petersfield in Hampshire, England.

It ednond founded in by John Haden Badley in reaction to the limitations of conventional Victorian schools. Bedales is one of the most expensive public schools in the UK. The Tatler Schools Guide used to cite Bedales as “a bohemian idyll with bite”,[3] and Demklins Good Schools Guide states that, although the school is “less distinctive than in the past”, it is “still good for ‘individuals’, articulate nonconformists, and people who admire such qualities”.

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As well as playing fields, For nearly a quarter of a century Le Play travelled around Europe, collecting a vast amount of material bearing on the social and economic condition of the working classes. Dashti was also an Iranian senator. Ali Dashti received a traditional religious education. He studied Islamic theology, history, Arabic and Persian grammar, and classical literature in madrasas in Karbala and Najaf both dmolins Iraq. He returned to Ddemolins in and lived in Shiraz, Isfahan, and finally in Tehran, dmeolins he became involved in politics of the day.

Rather than becoming a cleric, he became a journalist and published a newspaper Shafaq-e Sorkh in Tehran edmnd to He was a member of Majlis[1] at various times between and His criticism of allowing the Tudeh party into the cabinet and concessions to the Soviets landed him in prison in He was appointed a Senator in until the Islamic revolution in An Iranian newspaper reported his death in He founded and was headmaster of the progressive Abbotsholme School.

He spent four years at Goldolphin School in London until his parents’ deaths. He attended Birkenhead School — as a day-boy and he then was a boarder at Fettes College, Edinburgh — In he joined the radical Fellowship of the New Life in England and decided to establish a school for Paul de Rousiers 16 January — 28 March was a French social economist and industrial lobbyist. He undertook studies of society and economic organization in the United States, Britain and Germany, where he visited the rural areas, towns, cities, farms, mines and factories, and spoke to workers, owners, politicians and intellectuals to gain an understanding of the interplay of social and economic forces.

His work gained him considerable respect. In Paul de Rousiers became secretary-general of the French shipowners’ association, a position he held for most of the rest of his life.

Edmond Demolins – Wikipedia

In this role he proved a highly effective lobbyist. He also provided valuable information and legal services to the members, and helped in their negotiations with trade unions. He remained involved in social econom Robert Pinot 28 January — 24 February was a French sociologist from the conservative Le Playist school who became a highly effective lobbyist for heavy industry owners.

They brought with them a few adherents including Paul de Rousiers and Robert Pinot. Amongst the Compagnons, have demoline awarded posthumously,[2] 60 were not French at the time they were awarded[3] and six are demoilns. Savoyep. Taguieffpp. Edmond Demolins topic Edmond Demolins — was a French pedagogue. Member feedback about Edmond Demolins: Progressive education topic Demolind education is a pedagogical movement emond began in the late nineteenth century; it has persisted in various forms to the present.

Member feedback about Progressive education: Education theory Revolvy Brain revolvybrain. Member feedback about Ahmad Fathy Zaghlul: Egyptian politicians Revolvy Brain revolvybrain. Member feedback about Sultanzade Sabahaddin: Member feedback about Henri de Tourville: French sociologists Revolvy Brain revolvybrain. Social geography topic Social geography is edmnd branch of human geography that is most closely related to social theory in general and sociology in particular, dealing with the relation of social phenomena and its spatial components.

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Bedales School topic Bedales School is a co-educational, boarding and day independent school in the village of Steep, near the market town of Petersfield in Hampshire, England. Member feedback about Bedales School: Petersfield, Hampshire Revolvy Brain revolvybrain. French Roman Catholics Revolvy Brain revolvybrain.

Ali Dashti topic Ali Dashti Persian: Member feedback about Ali Dashti: Member feedback about Cecil Reddie: Paul de Rousiers topic Paul de Rousiers 16 January — 28 March was a French social economist and industrial lobbyist.

Member feedback about Paul de Rousiers: French economists Revolvy Brain revolvybrain. Robert Pinot topic Robert Edmon 28 January — 24 February was a French sociologist from the conservative Le Playist school who became a highly effective lobbyist for heavy industry owners.

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Conceptos Elementales del Materialismo Historico by Marta Harnecker, , available at Book Depository with free delivery. : Conceptos elementales del materialismo historico (Spanish Edition) () by Marta Harnecker and a great selection of similar New. Find great deals for Conceptos Elementales Del Materialismo Historico (spanish by Marta Harnecker. Shop with confidence on eBay!.

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KIMIA ANORGANIK II: KIMIA KOORDINASI Terjemahan Buku James E. Huheey – Inorganic Chemistry Principle Chapter 9, 10, and @article{utm, journal = {Jurnal Teknologi D}, year = {}, month Tiga ligan ketohidrazon telah berjaya disintesis melalui proses kondensasi bagi meningkatkan kuasa dan kekuatan eksplosif otot kaki atlit lompat jauh. sahaja sekadar pembinaan sebuah rig yang menyerupai keadaan di medan. jurnal. jurnalis. jurnalisme. jurnalistik. juru. jurubicara. juruh. jurung. jururawat. jurus kekritisan. kekuasaan. kekuasaannya. kekuasaanya. kekuatan. kekuatannya ligan. ligar. ligas. ligasi. ligat. ligatur. lightbulb. ligi. ligih. ligina. ligiositas. ligius medan. medang. mede. medeli. medi. media. medial. median . mediasi.

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Thank you for interesting in our services. We are a non-profit group that run this website to share documents. We need your help to maintenance this website. Please help us to share our service with your friends. Lulu Ciprutz Ajjah Category: Pada harihari awal kimia, mereka tampak tidak biasa karenanya disebut ion “kompleks” dan sepertinya menentang peraturan valensi yang kekuataan.

James E Huheey

Hari ini mereka terdiri dari sebagian besar penelitian anorganik saat ini. Meskipun teori ikatan biasa dapat diperluas untuk mengakomodasi senyawa ini, namun tetap memberikan masalah stimulasi untuk dipecahkan. Dalam pekerjaan sintetis mereka terus memberikan tantangan di laboratorium.

Bidang kimia bioinorganik yang berkembang pesat berpusat pada adanya senyawa koordinasi dalam sistem kehidupan. Studi modern tentang senyawa koordinasi dimulai dengan dua pria, Alfred Werner dan Sophus Mads Jorgensen.

Kedua pria tersebut adalah ahli kimia yang cerdik, tidak hanya di aspek sintetis atau laboratorium, tetapi juga di bidang interpretasi fenomena yang mereka amati dan oleh karena itu berfungsi sebagai protagonis, masing-masing memacu yang lain untuk melakukan eksperimen lebih lanjut untuk menambah bukti mengenai sudut pandangnya.

Dari sudut pandang kita setengah abad kemudian, kita dapat menyimpulkan bahwa Werner “benar” dan Jorgensen “salah” dalam menafsirkan bukti eksperimental yang mereka miliki. Memang, Werner adalah ahli kimia anorganik pertama yang dianugerahi Hadiah Nobel dalam bidang Kimiakontribusi Jorgensen tidak boleh diremehkan sebagai seorang eksperimentalis yang tidak ada duanya, dan seandainya dia tidak berprasangka oleh beberapa teori tentang arus valensi Pada masanya, dia mungkin telah mencapai hasil dan ketenaran yang sama dengan Werner.

Ini adalah texbook baik dari kimia historis maupun filosofi penemuan ilmiah, jadi diskusi ekstensif tentang kontroversi Werner-Jorgensen tidak akan ada lagi di sini, tapi secara singkat kita dapat menjelaskan masalah yang dihadapi oleh ahli kimia di bagian akhir abad kesembilan belas. Beberapa logam, bagaimanapun, menunjukkan kekuatan gabungan yang sulit untuk didamaikan dengan gambar sederhana ini. Namun klorida dari logam-logam ini akan bereaksi dengan amonia dimana valensi nitrogen dan hidrogen sudah terpenuhi: Empat kompleks amonia kobalt III klorida telah ditemukan dan dinamai menurut warnanya: Kompleks Warna Nama awal CoCl3.

Lebih jauh lagi, Werner mencatat bahwa reaktivasi ion klorida dalam keempat senyawa ini sangat berbeda. Penambahan nitrat perak menghasilkan jumlah prec yang berbeda Korelasi antara jumlah molekul amonia yang ada dan jumlah ekuivalen perak klorida yang diendapkan menyebabkan Werner menjadi kesimpulan berikut: Senyawa M NH3 6X3 dengan kehilangan satu molekul amonia. Dari kesimpulan ini, Werner mendalilkan mungkin bagian terpenting teorinya: Untuk menggambarkan kimia kobalt yang rumit, oleh karena itu seseorang harus mempertimbangkan tidak hanya keadaan oksidasi logam tetapi juga nomor koordinasinya.

Beberapa hasil dari pekerjaan ini tercantum dalam Tabel 9. Kontribusi penting kedua yang Werner buat untuk mempelajari kimia koordinasi adalah dalil bahwa ikatan ke ligan tetap berada di luar angkasa dan oleh karena itu dapat diperlakukan dengan penerapan prinsip-prinsip struktural.

Dengan menggunakan angka dan Diterjemahkan oleh Denti Suastikasari sifat isomer yang diperoleh, Werner dapat menetapkan struktur geometrik yang benar ke banyak senyawa koordinasi jauh sebelum metode eksperimen langsung tersedia untuk penentuan struktur. Metode Werner adalah yang sebelumnya digunakan oleh ahli kimia organik untuk menjelaskan struktur benzenes tersubstitusi, yaitu penghitungan isomer.

Tiga pengaturan seperti itu muncul dalam pikiran: Yang terakhir berhubungan erat dengan yang pertama, yang dibentuk oleh rotasi salah satu wajah trigonal sebenarnya, oktahedron dapat dianggap sebagai anti-prisma trigonal.

James E Huheey – Free Download PDF

Untuk kompleks “disubstitusikan”, MA4B2, susunan planar memberi tiga isomer, susunan orto, meta, dan para kimia organik yang sudah dikenal. Prisma trigonal menghasilkan tiga isomer juga, namun hanya ada dua pengaturan oktahedral untuk formulasi ini. Jumlah total isomer yang diharapkan untuk setiap susunan geometris bersama dengan hasil eksperimen untuk berbagai komposisi tercantum pada Tabel 9. Dalam setiap kasus yang diselidiki Werner, jumlah isomer yang ditemukan sama dengan yang diharapkan untuk kompleks oktahedral.

Meskipun korelasinya sempurna, harus diingat bahwa kehadiran dua bukan tiga isomer yang dikenal untuk senyawa ini dan yang lainnya merupakan bukti negatif mengenai struktur kompleks ini. Meskipun Werner bekerja dengan hati-hati dan memeriksa banyak sistem, selalu ada kemungkinan, memang kecil, bahwa isomer ketiga telah lolos dari pendeteksiannya.

Kegagalan untuk mensintesis senyawa, untuk mengamati suatu sifat tertentu, atau untuk menghasilkan reaksi tertentu tidak akan pernah menjadi bukti positif dari tidak adanya senyawa, properti, atau reaksi tersebut.

Ini mungkin hanya mencerminkan beberapa kegagalan teknik dari ahli kimia.

Salah satu contoh terkenal dari kegagalan bukti negatif adalah penggulingan dogma dari inertness kimiawi gas mulia lihat Bab 15 Diterjemahkan oleh Denti Suastikasari Namun, Werner dalam kesimpulannya mengenai geometri oktahedral medwn koordinasi bilangan 6 untuk kobalt dan platinum IV.

Dia juga benar, dan pada pijakan logis yang lebih kuat, dalam ljgan geometri planar planar ke kompleks paladium dan platinum dari fakta bahwa dua isomer telah diisolasi dari senyawa formula MA2B2.

Struktur alternatif yang paling mungkin, tetrahedron, hanya akan menghasilkan satu isomer untuk komposisi ini. Hal ini biasanya disebut sebagai teori ikatan valensi dari senyawa koordinasi. Hal ini terkait erat dengan hibridisasi dan geometri senyawa nonkompleks seperti yang dibahas pada Bab 5.

Dari sudut pandang valensi pandang, pembentukan jrunal adalah reaksi antara basa Lewis ligan dan asam Lewis ion logam atau logam dengan Diterjemahkan oleh Denti Suastikasari pembentukan ikatan kovalen koordinasi atau datif antara ligan dan logam.

Kompleks dari pd11 dan Pt11 biasanya 4 koordinat, planar persegi, dan diamagnetik, dan susunan ini sering ditemukan di kompleks Ni11 juga. Karena keadaan dasar ion-ion ini bersifat paramagnetik 3Fligan dalam kompleks diamagnetik ini akan menyebabkan pasangan dua elektron asing.

Pauling mengatakan, bahwa ini terjadi melalui llgan satu orbital d oleh ligan. Itu biasanya mewakili orbital logam oleh kotak atau lingkaran dengan tujuan menghitung liban elektron logam yang disumbangkan oleh ligan: Pauling mengatakan agar kompleks ini melibatkan sp3 hibrida: Aturan ini, “kriteria magnetik tipe obligasi”, terbukti sangat berguna selama beberapa tahun, tapi sekarang kita tahu bahwa itu bisa menyesatkan, yang mengindikasikan salah satu kelemahan interpretasi VB yang disederhanakan tentang ikatan dalam kompleks.

Werner mensintesis sejumlah besar kompleks ini. Dengan demikian dapat dirumuskan sebagai berikut: Penemuan bahwa kompleks paramagnetik Co dapat dibentuk CoF, memiliki empat elektron yang tidak berpasangan memerlukan penyesuaian teori. Pauling mengatakan agar ion fluoride bisa melewati orbital 4d “outher”.

Seperti hibrida, 3sp34d2, akan memiliki simetri identik dengan hibrida 3d2sp3 yang ada di atas. Ion heksafluorokobaltat Jurjal dapat diformulasikan sebagai: Prinsip electroneutrality dan ikatan belakang Salah satu kesulitan yang nyata dengan asumsi VB tentang sumbangan elektron dari ligan ligan lewis ke ion logam asam lewis adalah penumpukan muatan negatif formal pada logam.

Karena masalah ini, dalam satu bentuk atau lain, dalam semua perawatan lengkap senyawa koordinasi, diskusi berikut sesuai untuk semua metode berikut. Dari sudut pandang muatan formal, kobalt akan menjadi negatif. Namun, pauling menunjukkan dua alasan mengapa logam tidak benar-benar ada dengan kekuafan negatif yang tidak terwujud. Pertama, karena atom donor pada ligan, pada umumnya, atom yang sangat elektronegatif seperti halogen, N dan O, elektron tidak akan dibagi rata antara logam dan ligan, sehingga mendorong muatan positif pada logam untuk membantu mengimbangi yang tidak menguntungkan.

Pauling mengatakan bahwa kompleks akan paling stabil ketika elektronegativitas ligan sedemikian rupa sehingga logam mencapai kondisi yang pada dasarnya netral. Aturan praktis ini dikenal sebagai prinsip electroneutrality. Pauling dan rekan kerja10 telah membuat perhitungan semiquantitative yang menghubungkan kestabilan kompleks dengan muatan pada atom logam pusat.

Karena perhitungan ini melibatkan perkiraan yang sangat kasar, metode ini tidak tepat untuk diaplikasikan dan metode perhitungan tidak perlu diperhatikan. Nilai menunjukkan secara kualitatif bagaimana penumpukan muatan negatif yang berlebihan pada logam dapat mengganggu kestabilan kompleks.

Beberapa total tipenya adalah: Meskipun nilai di atas tidak boleh dianggap terlalu harfiah, mereka menunjukkan beberapa prinsip kualitatif dalam pembentukan senyawa koordinasi. Metode yang digunakan untuk memperkirakan biaya ini hanya perkiraan, dan metode eksperimental yang digunakan untuk mengukur kepadatan muatan tidak terlalu akurat, namun juga mengkonfirmasi kebenaran penting dari prinsip electroneutrality. Dalam enam kompleks kobalt IIInilai absolut muatan pada atom kobalt ditentukan secara eksperimen lihat halaman 10a sampai rata-rata 0,6 elektron.

Diterjemahkan oleh Devi Nurwidya Wahyuni – Prinsip electroneutrality nampaknya paling mudah diterapkan pada kompleks yang tidak stabil karena penumpukan densitas elektron yang berlebihan pada logam. Meskipun energi ionisasi dari sebuah atom logam juga harus mencegah pembentukan kompleks dengan muatan positif yang besar pada logam, muatan tersebut menyebabkan peningkatan energi ikatan Madelung “ionik” yang dapat mengimbangi dan membantu menstabilkan kompleks.

Adalah mungkin untuk menemukan logam dalam keadaan oksidasi tinggi di oksida dan kompleks fluorida seperti CoF, MnF, RuF6- CrO3F- MnO4 Dalam karbonil, nitrosil, dan senyawa terkait, logam biasanya ada dalam keadaan oksidasi rendah dan terikat pada unsur elektronegatifitas yang cukup rendah.

Kompleks ini tidak dapat stabil jika logam tidak memiliki cara kedua untuk menurunkan kerapatan elektronnya. Pauling mengatakan bahwa mekanisme untuk delokalisasi kerapatan elektron elektron dapat ditemukan pada “back bounding” atau partial. Pemeriksaan yang lebih tepat terhadap proses ini menunjukkan bahwa delokalisasi kerapatan elektron terjadi melalui tumpang tindih orbital d pada logam dengan orbital atom karbon sehingga membuatnya tidak tersedia untuk ikatan pi ke oksigen sedangkan teori orbital molekul akan berbicara dalam hal tumpang tindih orbital logam dengan ikatan pi orbital11 karbon monoksida lihat gambar 3.

Logam, yang sudah dalam keadaan oksidasi rendah, terhalang untuk menjadi terlalu negatif. Pembentukan ikatan pi jenis ini akan dibahas lebih jauh nanti di bab ini. Kekuatan dan kelemahan pendekatan ikatan valensi Sampai sekitar 30 tahun yang lalu, teori ikatan valensi hampir satu-satunya yang diterapkan pada senyawa koordinasi oleh ahli kimia. Pada dekade berikutnya sebuah revolusi terjadi, dan hari ini beberapa ahli kimia anorganik menggunakan teori ikatan valensi sederhana dalam diskusi kompleks ini.

Bukan karena teori ikatan valensi salah – tidak. Teori ikatan valensi senyawa kompleks masih hidup Pauling saat ini sedang menafsirkan beberapa sifat yang tidak biasa dari senyawa koordinasi dalam istilah ikatan valensi. Oleh karena itu, siswa tersebut harus menyadari teknik dan terminologinya, walaupun ahli kimia anorganik masa kini memerlukan sudut pandang teoritis yang jauh lebih luas untuk menafsirkan secara memadai data eksperimen yang dipresentasikan oleh kimia koordinasi.

Perkembangannya kontemporer dengan pendekatan Vass dari Pauling. Meskipun digunakan sampai batas tertentu oleh fisikawan, sebagian besar tidak diketahui ahli kimia sampai tahun an. Untuk periode 20 tahun, semua koordinasi kimia ditafsirkan dalam hal teori ikatan valensi.

Popularitas yang terakhir dinikmati CFT sebagian besar disebabkan oleh fakta bahwa teori ikatan valensi menjawab pertanyaan yang oleh para ahli kimia pada periode itu menanyakan tentang geometri dan kerentanan magnetik ion kekjatan yang terisolasi.

Seperti Van Vleck menunjukkan pada awal dan seperti yang akan dibahas kemudian, teori ikatan valensi dan kristal adalah kasus khusus dari perlakuan orbital molekul yang lebih umum.

Diterjemahkan oleh Devi Nurwidya Wahyuni – Sama seperti teori medan kristal yang sebagian besar menggantikan teori ikatan valensi dalam memperlakukan senyawa koordinasi, pada gilirannya diganti teori ikatan valensi dalam mengobati senyawa koordinasi, pada gilirannya digantikan oleh teori orbital molekul. Namun, dan inilah yang penting, CFT secara konseptual begitu sederhana, argumen simetrisnya identik dengan dan energik dan ramalannya yang hampir sama dengan teori orbital molekul sehingga jauh dan jauh cara terbaik bagi seorang newcorner untuk mendekati modern.

Kita akan melanjutkan pengobatan teori yang lebih baru secara bergantian.

Tidak ada cara unik untuk mewakili orbital d lima, namun representasi yang paling nyaman ditunjukkan pada buah ara. Sebenarnya, ada enam fungsi gelombang yang bisa ditulis untuk orbital yang memiliki bentuk empat lobus khas misalnya dxy. Karena hanya ada lima d orbital yang memiliki realitas physisical, orbital d kelima dz2 harus merupakan kombinasi linear dua “orbitsls” lainnya dz2 -y2 dan dz2 – x2.

Edukasi,46, Oleh karena itu, karena keduanya memiliki kerapatan elektron tinggi di sepanjang sumbu z, orbital memiliki kerapatan elektron dalam jumlah besar yang terkonsentrasi di sepanjang sumbu.

Karena salah satu fungsi gelombang komponen dimaksimalkan sepanjang sumbu x kekuayan yang lainnya sepanjang sumbu y16 resultan memiliki torus kerapatan elektron di bidang xy. Teori medan kristal murni mengasumsikan bahwa satu-satunya interaksi antara ion logam dan ligan adalah elektrostatik “ionik”.


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M. Metcalf, J. Reid, Alejandro Garcia, Susan McKay, and Wolfgang Christian Fortran 90 Explained and FORTRAN 77 for Engineers and Scientists: Includes. Request PDF on ResearchGate | Fortran 90/95 explained. The optimizer and objective function are written in Fortran 90 (Metcalf and Reid ), and the. The success of Fortran as the predominant programming language in the field of scientific and numerical computing is due, in part, to the steady evolution of the.

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Fortran 95/ Explained – Michael Metcalf, John Reid, Malcolm Cohen – Oxford University Press

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Fortran 90/95 explained / Michael Metcalf, John Reid – Details – Trove

The success of Fortran as the predominant language in the field of scientific and numerical computing is due, in part, to its steady evolution. The latest version, Fortran 95, was published in and included new features from Fortran 90 for array processing, abstract data types, modules, and pointers, as well as additional features foetran keep it aligned with High Performan The success of Fortran as the predominant language in the field of scientific and numerical computing is due, in part, to its steady evolution.

The latest version, Fortran 95, was published in and explzined new features from Fortran 90 for array processing, abstract data types, modules, and pointers, as well as additional features to keep it aligned with High Performance Fortran. The Fortran explaihed material is now fully integrated with the material on Fortran 90, while the text carefully maintains the distinction between the two language levels.

It include new chapters on two important changes: A complete and authoritative description of Fortran 90 and 95, this book is intended for both new and experienced users. PaperbackSecond Editionpages.

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FORTRAN 90/95 Explained

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